|
|
S-adenosyl-L-methionine + 3-demethylubiquinol-10 <=> H+ + ubiquinol-10 + S-adenosyl-L-homocysteine
|
2.1.1.64
3-demethylubiquinol 3-O-methyltransferase
|
–
|
|
BRENDA:
BS407325
MetaCyc:
RXN-9237
|
|
|
|
H+ + 5-all-trans-decaprenyl-4-hydroxy-3-methoxybenzoate <=> 3-(all-trans-decaprenyl)-1-methoxybenzene-2-ol + CO2
|
4.1.1
|
–
|
|
MetaCyc:
RXN-9285
|
|
|
|
3-(all-trans-decaprenyl)-1-methoxybenzene-2-ol + O2 + NADPH + H+ <=> all_trans-decaprenyl-2-methoxy-6-1,4-benzoquinol + H2O + NADP+
|
1.14.13.M56
|
–
|
|
MetaCyc:
RXN-9234
|
|
|
|
(2E,6E)-farnesyl_diphosphate + isopentenyl_diphosphate <=> di-trans-poly-cis-decaprenyl_diphosphate + diphosphate
|
2.5.1.87
ditrans,polycis-polyprenyl diphosphate synthase [(2E,6E)-farnesyl diphosphate specific]
2.5.1.91
all-trans-decaprenyl-diphosphate synthase
|
–
–
|
|
BRENDA:
BR49323
KEGG:
R09249
MetaCyc:
RXN-21509;
RXN-9106
|
|
|
|
3-decaprenyl-4-hydroxybenzoate + O2 + NADPH + H+ <=> 5-all-trans-decaprenyl-3,4-dihydroxybenzoate + H2O + NADP+
|
1.14.13.M81
|
–
|
|
MetaCyc:
RXN-9279
|
|
|
|
S-adenosyl-L-methionine + all_trans-decaprenyl-2-methoxy-6-1,4-benzoquinol <=> H+ + 6-methoxy-3-methyl-2-all-trans-decaprenyl-1,4-benzoquinol + S-adenosyl-L-homocysteine
|
2.1.1.201
2-methoxy-6-polyprenyl-1,4-benzoquinol methylase
|
–
|
|
MetaCyc:
RXN-9235
|
|
|
|
S-adenosyl-L-methionine + 5-all-trans-decaprenyl-3,4-dihydroxybenzoate <=> H+ + 5-all-trans-decaprenyl-4-hydroxy-3-methoxybenzoate + S-adenosyl-L-homocysteine
|
2.1.1.114
polyprenyldihydroxybenzoate methyltransferase
|
–
|
|
BRENDA:
BS407329
MetaCyc:
RXN-9282
|
|
|
|
6-methoxy-3-methyl-2-all-trans-decaprenyl-1,4-benzoquinol + O2 + reduced_acceptor <=> 3-demethylubiquinol-10 + H2O + acceptor
|
1.14.99.60
3-demethoxyubiquinol 3-hydroxylase
|
–
|
|
MetaCyc:
RXN-9236
|
|
|
|
decaprenyl_diphosphate + 4-hydroxybenzoate <=> 3-decaprenyl-4-hydroxybenzoate + diphosphate
|
2.5.1.39
4-hydroxybenzoate polyprenyltransferase
|
–
|
|
MetaCyc:
RXN-9230
|
|